Abstract
1. The reaction between 1-chloro-1,3,5,7-tetramethyl-2,4,6,8-tetrathioprotoadamantane and mercapto-compounds or weakly basic amines produces sulfides and amine derivatives with the protostructure. When (II) reacts with strongly basic amines, dehydrochloridation takes place. 2. The reaction between 9-bromo-1,3,5,7-tetramethyl-2,4,6,8-tetrathioadamantane and thioacetic acid in ethanol in presence of alkali proceeds by regrouping, with the formation of the thiolacetate of 2,4,6,8-tetra-thioprotoadamantane.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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