Abstract
Heterogeneous equilibria in the nickel perchlorate–acetamide–perchloric acid–water quaternary system at 25°С were studied by studying solubility. The crystallization regions were determined for the initial solid components, eutonic compositions of the ternary systems constituting the quaternary system, binary compounds of acetamide with nickel perchlorate and perchloric acid, and also two new coordination compounds containing simultaneously nickel perchlorate, acetamide, and perchloric acid: Ni(ClO4)2 · 4CH3CONH2 · HClO4 and Ni(ClO4)2 · 2CH3CONH2 · HClO4.
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