Abstract
The benzyl radical was formed by the photolysis and γ-irradiation of organic rigid matrices (hydrocarbons, 2-methyltetrahydrofuran and ethanol) containing benzyl chloride, and its electronic spectra were examined by a fluorescence spectrometer. It is shown that the spectra are modified by a chloride anion situated close to a benzyl radical, when it was formed through dissociative electron attachment to benzyl chloride in the non-polar matrix.
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