Abstract
<p>The interaction between propylene and H<sub>2</sub>O on Ru-Co/SiO<sub>2</sub>-catalyst was studied. It was determined that the process of the water addition to olefin molecule is carried out with n-propanol, i-propanol and acetone formation. For clarification of the adsorption mechanism of propylene on Ru-Co-clusters the quantum- chemical calculation of interaction between it and Ru-Co, Ru-Ru, Co-Co clusters were carried out.</p>
Highlights
Ruthenium is the catalysts for many chemist reactions
We studied the Ru-containg catalysts in Fisher-Tropsch synthesis [1,2]
The adsorption model of the propylene on Ru, Co and Ru-Co-clusters has been studied by use quantum-chemical methods
Summary
Ruthenium is the catalysts for many chemist reactions. It activites double C=C-bond and forms fine conditions for the process of hydrogen addition and the other reactions. Interaction Between Propylene and H2O over Ru-Co/SiO2 -Catalysts of Clusters Type The interaction between propylene and water on Ru-Co/SiO2 catalyst takes place at relavety high pressure (0,9 MPa) and temperature (>573K).
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