Interaction between Hydrogen-Donor and Nondonor Solvents in Direct Liquefaction of Bulianta Coal

Abstract

Solvent plays two very important roles in coal liquefaction: (1) Physically, it serves as a medium for coal transport and heat transfer, and (2) chemically, it serves as an important source of transferable hydrogen (hydrogen donor) and hydrogen shuttle between hydrogen and coal. In this work, eight types of non-hydrogen-donor solvents, namely, decalin, 1-methylnaphthalene, naphthalene, fluorene, anthracene, phenanthrene, pyrene, and fluoranthene, were examined in combination with the hydrogen-donor solvent tetralin in the liquefaction of Bulianta coal to clarify the interactions between the hydrogen-donor and non-hydrogen-donor solvents and the mechanism of hydrogen transfer. In the absence of a catalyst, the mixed solvents of tetralin with phenanthrene, pyrene, and fluoranthene showed favorable effects on coal conversion and oil yield compared with pure tetralin, regardless of whether the reactions were conducted in a H2 or N2 atmosphere. The reactions of non-hydrogen-donor solvents with tetralin showed ...