Intensity calculations of the VUV and UV photoabsorption and photoionisation of CF 3Cl

Abstract

Absorption oscillator strengths and photoionisation cross-sections for CF 3Cl from its ground state are reported. The molecular-adapted Quantum Defect Orbital (MQDO) method has been employed in the calculations. Partial differential oscillator strengths for the different Rydberg series that constitute the ionisation channels of CF 3Cl, as well as the photoionisation cross-sections, from its ground state are reported. The calculated cross-sections conform fairly well with experimental and theoretical values found in the literature.