Intensified wheat husk conversion employing energy-efficient hybrid electromagnetic radiations for production of fermentable sugar: process optimization and life cycle assessment.

Abstract

This article reports an energy-efficient green pathway for the sustainable conversion of an abundant agro-residue viz. wheat husk (WH) into fermentable sugar (FS). The intensification effects of tungsten-halogen (TH) (150 W) and ultraviolet (UV) (100 W) irradiations on the pretreatment and subsequent hydrolysis of WH have been experimented with and optimized by Taguchi Orthogonal Design Array (TODA). In this study, two commercial catalysts, viz. Amberlyst-15 (A15) and nano-anataseTiO2 (NAT) have been used in varying concentrations for the WH conversion process in a novel TH-UV radiated rotating reactor (THUVRR). At optimized peracetic acid pretreatment conditions [90 °C reaction temperature; 1: 2.5 w/w of WH: H2O2; 1: 5 w/w of WH: CH3COOH (1 M); 2h of reaction time] maximum 20.2 wt. % FS yield and 15 wt. % isolated lignin (purity 97.6 %) were obtained. Subsequently, the pretreated WH (PWH) was hydrolyzed at optimized conditions [(700C reaction temperature; 7.5wt. % catalyst concentration (1:1 w/w A15: NAT); 1: 30 w/w of WH: water; 30 min reaction time)] in THUVRR to render maximum yield of FS (36.9g/ L) (67.4 wt. %), which was significantly greater than that obtained (20.2g/ L) (38.42 wt. %) employing a conventional thermal reactor (CTR). Besides, the energy consumption was 70% more in CTR (500 W) in comparison with THUVRR (150 W); thus, demonstrating markedly superior energy-efficiency vis-à-vis appreciable improvement in FS yield in THUVRR over CTR. Overall sustainability of the process analyzed by LCA proved the approach to be energy-saving and environmentally benign and is expected to be applicable to similar lignocellulosic agro-wastes.