Integration of nanosized zero-valent iron particles addition with UV/H 2O 2 process for purification of azo dye Acid Black 24 solution

Abstract

The challenging national effluent standards for color and organic concentration enforce the industrial concern most the techniques providing fast and efficient solution for the strenuous dye wastewater treatment before outflow. The best remediation technique pursuit is urgently demand for the industrial, government, academia and community. In this study, a di-azo dye, C.I. Acid Black 24, synthesized wastewater was successfully removed synchronously its total color and total organic carbon (TOC) using an integrated innovation technology by coupling the zero-valent iron (ZVI) nanoparticles with UV/H 2O 2 oxidation process. The nanosized ZVI (NZVI) primarily reduced color successfully following coupling UV/H 2O 2 oxidation process for the residual organic mineralization resulting reduction with oxidation process (Re–Ox) for total color removal and organic mineralization. From the experimental data, the Re–Ox process consumed shorter time than UV/H 2O 2 oxidation process alone to obtain total color removal of dye wastewater. Moreover, the residual TOC of dye wastewater after NZVI reduction from 45 to 100% was effectively mineralized by UV/H 2O 2 process. By using proposed processes integration with NZVI dosage of 0.3348 g l −1 and hydrogen peroxide concentration of 23.2 mM, in only 10 min the AB24 color was complete eliminated and in 90 min the TOC was 93.9% removed. Thus, the coupling Re–Ox process was developed to provide a superior solution for dye wastewater treatment.