Abstract

This chapter describes a unique use of existing quality control (QC)-measured resin properties to predict relative molding cycle times for high-flow polyethylene (PE) resins. A resin manufacturer changes polymerization catalyst systems, modifies reactor configuration, or adjusts reactor-operating parameters such as temperature, ethylene, and hydrogen concentrations to vary molecular weight (MW) and molecular weight distribution (MWD). Melt index is measured in the QC lab and is used as an indication of resin molecular weight. It is defined as the number of grams of polymer extruded in ten minutes as measured by ASTM Method D1238. The higher melt index results in the lower molecular weight and melt viscosity, which ensures that the resin processes more easily. Melt flow ratio is a calculated QC lab number that is used as an indication of MWD. It is calculated by dividing a melt index measured at a high shear rate by a melt index measured at a low shear rate.

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