Integrating stabilizer efficiency of secondary antioxidants to thermal, rheological, optical characterization and filterability study of polypropylene

Abstract

Abstract The framework of the present study is based on investigation of different types of phosphorus based secondary antioxidants and their role in stabilization of polypropylene. Three different chemical entities i.e., Tris (2,4-di-tert-butylphenyl) phosphite, Tetrakis (2,4-di-tert-butylphenyl)-4,4-biphenyldiphosphonite and Bis (2,6-di-tert-butyl-4-methylphenyl pentaerythritol-diphosphite) have been studied for its efficiency as a secondary antioxidants or processing stabilizer. Thermal stability of polymer is predicted using degradation kinetics study and correlated with it’s optical, thermal and rheological response. To further evaluate performance of secondary antioxidants, thermogravimetry analysis was performed for polypropylene at three different heating rates and processed for iso-conversional analysis to get the kinetic parameters. Oxidation induction data and kinetic parameters have been related with efficiency of the stabilizers. Filtration study was also carried out to understand the efficacy of stabilizers during secondary process. Die pressure build up in filtration study is quantified and related with performance of secondary antioxidants.