Integrating adsorption and in situ advanced oxidation for the treatment of organic wastewater by 3D carbon aerogel embedded with Fe-doped carbonitrides.

Abstract

Wastewater containing organic pollutants with high toxicity and poor biodegradability poses a considerable threat to human health and the ecosystem. Although adsorption and advanced oxidation processes (AOPs) are currently the most widely used technologies for wastewater treatment, limitations of these two independent processes make the treatment effect unsatisfactory. Herein, a system of integrating adsorption and subsequent in situ AOPs is established by a 3D carbon aerogel embedded with Fe-doped carbonitrides (Fe-NC/CAG). The SEM and BET analysis demonstrate that Fe-NC/CAG possesses porous structures with a specific surface area of 518.7 m2/g. The XRD result indicates the formation of Fe0 and Fe3O4 in Fe-NC/CAG. The impacts of operational parameters such as Fe-NC/CAG dosage, pollutants concentration, temperature, initial pH, and inorganic ions on the adsorption efficiency are investigated. The adsorption kinetics is predominantly based on the pseudo-second-order model. After adsorbing organic pollutants, the Fe-NC/CAG is immersed in peroxymonosulfate (PMS) solution. The adsorbed pollutants are in situ degraded by PMS-based AOPs, leading to the regeneration of Fe-NC/CAG. At optimum conditions, the integrating process established by Fe-NC/CAG achieves over 90% removal of antibiotics, phenolics, and dyes as well as keeps stable performance even after 6 cycles. This integrating adsorption and AOPs system is expected to open up a rich field for wastewater treatment.