Integrated synthesis and ripening of AgInS2 QDs in droplet microreactors: An update fluorescence regulating via suitable temperature combination

Abstract

Aqueous phase synthesized ternary I–III–VI2 Quantum dots (QDs) are getting more and more attention in biology researches, for their good biocompatibility and easy-to-adjust fluorescence properties. However, the quantum yield (QY) of these aqueous phase synthesized QDs are often pretty low, which seriously hindered their further applications in this field. In general, the ripening of the QDs helps to enhance their QY, closely related to the ripening temperature. But it is still hard to precisely control the fluorescence performance of the QDs products, due to the difficulties in precise temperature control and cumbersome temperature adjusting operations in batch reactors. Here we proposed an integrated droplet microfluidic chip for the automated and successive AgInS2 QDs synthesis and ripening, with both temperatures controlled independently, precisely but easily. Taking advantage of the space-time transformation of the droplet microfluidic chips, the suitable temperature combination for AgInS2 QDs synthesis and ripening was studied, and the high-performance AgInS2 QDs were obtained. In addition, the reason for the decrease of QY of AgInS2 QDs at higher ripening temperature was also explored.