Insulating property of polypropylene nanocomposites filled with nano-MgO of different concentration

Abstract

Polypropylene (PP) has special advantages in replacing conventional crosslinked polyethylene (XLPE) to be insulation material of power cable. In order to reveal the effects of nano-filler addition on PP, five kinds of experiments, namely TEM, DSC, breakdown strengths (BDs), space charge and dielectric measurement were investigated to evaluate the insulating properties of PP and its nanocomposites with surface-treated nano-MgO of different concentration. It is revealed that, with the addition of nano-MgO, favorable dispersibility of nano-filler and significant increase of crystallinity of polymer are observed. BDs under dc voltage increase apparently with loading of nano MgO, but when the nano concentration reaches higher than 1 wt%, the BDs have a slight decline compared with 1 wt%. It is clarified that space charge and electric field distortion are well restricted with the addition of nano-MgO, while this effect is not obvious with the nano concentration reaches 6 wt%. Permittivity has trends of increase with the rise of temperature at first and then decrease when the temperature reaches about 333 K, and the addition of nano-filler MgO could also decrease permittivity. When the nano-filler concentration reaches high, dielectric loss increases to a high level. Low nano-filler concentration in MgO/PP shows better electrical insulation properties compared with PP and high nano-filler concentration composites.