Insights into the structure–performance relationship in La–Y–Ni-based hydrogen storage alloys

Abstract

La–Y–Ni-based alloys with different phase structures possess various physicochemical properties and thereby different hydrogen storage performances. In this work, the hydrogen storage and electrochemical properties of LaY1·9Ni10Mn0·5Al0.2 alloys with different phase structures (2H-A2B7, 3R-A2B7 and 2H-A5B19) are investigated. All the investigated phases present two plateaus in pressure-composition-temperature (PCT) curves, which is induced by the different hydrogen location (A2B4 or AB5) during the hydrogen absorption process. All of the LaY1·9Ni10Mn0·5Al0.2 series alloys possess good hydrogen storage capacities and electrochemical properties. The cyclic stability of the alloys is determined by the anti-corrosive properties of the alloys to electrolyte, neither the phase transition nor the previously believed pulverization. This work, by systematically investigating phase transitions during the annealed process and elucidating the key factors of influencing the cyclic stability, is useful for the design of La–Y–Ni-based alloy for the application of hydrogen storage and beyond.