Insights into the Influence of Tensile and Compressive Strain on the Microstructure and Corrosion Performance of 304 L Stainless Steel

Abstract

The effects of tensile and compressive strain, originating from U-bent deformation, on the corrosion behavior of 304 L stainless steel were studied via analyses of the material’s microstructure and electrochemistry in a 3.5% NaCl solution. In contrast with the as-received 304 L steel with the largest grain size, the deformed 304 L material with a small grain size had the lowest number of Σ3 grain boundaries and an overall low fraction, with special low-Σ values (≤29). Moreover, the dislocation density increased to 1.13 × 1016/m2 and 1.4 × 1016/m2 for the tensile and compressive 304 L steel testing, respectively. The decrease in Epit and increase in ipit suggested that there was a decrease in anti-corrosion properties due to tensile and compressive deformation. This might be attributed to the higher plastic strain found in deformed 304 L steel, which can induce the rupture of passive film and have a harmful influence on corrosion resistance. In particular, the compressive 304 L steel with the highest content of deformed grains (42.12%) promoted the formation of microgalvanic cells, thereby facilitating the nucleation of pits. Then, these pits grew to a large size through grain shedding. Subsequently, massive chloride ions were generated during metal dissolution and diffused along grain boundaries, which promoted the initiation and propagation of intergranular corrosion cracks.