Abstract
CP or CP? One-electron oxidation of Li/Cl phosphinidenoid complexes led to the discovery of transient P-chlorophosphanyl complexes 1. Subsequent cross-coupling and rearrangement or elimination reactions yielded 2 and 3; the latter is the first structurally characterized phosphaquinomethane complex. ESR spectroscopy and DFT calculations support the existence of short-lived P-centered radicals.
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