Insights into Europa's ocean composition derived from its surface expression

Abstract

The global ocean believed to exist beneath Europa's thick ice shell is often cited as one of the most likely places in the solar system to find evidence of extraterrestrial habitable environments or even extant life. However, given the technical challenges and the costs associated with outer solar system exploration, direct analysis of the ocean appears unlikely in the foreseeable future. Therefore, constraints on the chemical composition of the ocean will need to be inferred, for example, from analysis of the surface ice, either via remote sensing or landed surface missions. In this paper, we combine our recent body of work studying the chemistry of frozen putative Europa ocean brines with new experiments to develop predictions of the sequence by which the hydrated minerals form when a four-ionic component ocean (Na+, Cl−, Mg2+, and SO42−) freezes as a function of relative ionic concentrations and pH. This in turn provides a means to begin linking observed surface chemistry and the chemical environment of the subsurface ocean as well as insight into endogenic versus exogenic origin of detected species.