Abstract
The study addresses the formation of secondary hydrochar and the morphology of secondary microparticles from black liquor. The black liquor solution was hydrothermally converted at 350 °C and 16.5 MPa in batch reactors running from 15 min to 24 h at different heating and cooling rates. Spherical carbon microparticles were obtained at a short reaction time (< 90 min) and then coalesced to form aggregates. At a very long reaction time (24 h), spherical carbon microparticles were obtained once again. The carbonaceous solid was enriched in carbon during the first 4 h of reaction. In parallel, the concentrations of total organic carbon and total phenols in the solution decreased drastically. The formation of solids was mainly due to chemical reactions occurring during the first 4 h. Subsequent changes in the solids were mainly due to physical reorganization since the chemical compositions of solutions were almost stable.
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