Abstract

Based on a one-year field investigation of disinfection by-products (DBPs) in large scale water distribution system (LSWDS), the various characteristics of DBPs together with their correlation with booster chlorination were elaborated through ArcGIS model. Furthermore, the effects of booster chlorination on DBP formation were investigated through simulated experiments. Residual chlorine showed a strong relationship with occurrence of different DBPs in LSWDS, and the yield of DBPs increased significantly after booster chlorination. The simulated chlorination experiments showed that diminution of the ratio of primary to secondary (booster) chlorination dosage, and delaying the secondary chlorine addition reduced the generation of DBPs during water conveyance. The yield concentrations of THMs and HAAs obviously increased after booster chlorination. The correlation between HAAs and chlorine dosage is weaker in the field research than in the simulation experiment while THMs had a positive correlation with the chlorine addition in both field research and simulation experiment.

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