Insights and perspectives on PVDF/MgO NCs films: Structural and optical properties for optoelectronic device applications

Abstract

In the current investigation, pure polyvinylidene fluoride (PVDF) and PVDF-MgO nanocomposite (NC) thin films are fabricated via solvent casting method using PVDF as a polymer matrix with different proportions of magnesium oxide (MgO) (0.5–2 wt%). The structural, morphological and optical properties of the prepared polymer NCs are studied by using XRD, FTIR, SEM, Raman and UV–Vis spectroscopy techniques. The α and β phases are detected in XRD measurements. MgO powder peaks are in good agreement with the reported literatures. The average crystallite size, lattice strain, and dislocation density of the prepared thin films are estimted by using Williamson-Hall (W-H) plot. SEM micrographs reveals the fluorine-containing carbon chain network that forms the spherulite and fiber-like structure in the PVDF/MgO NCs films. The Raman and FTIR spectra of PVDF/MgO and pure PVDF films are also evaluated. UV–Vis spectroscopy is used to examine the absorbance, transmittance, and reflectance spectra of pure PVDF and PVDF/MgO NCs thin films. The dipole polarization interaction causes the absorption coefficient, direct band gap, indirect band gap, optical activation energy, and skin depth of pure PVDF and PVDF/MgO thin films to decrease, whereas increasing the dielectric constant at high frequency value, refractive index, loss, optical conductivity, and dielectric constant per effective mass of NCs films. Optical dispersion parameters are estimated by the single oscillator model. The obtained results can be employed in the possible applications in supercapacitors. The method used for the preparation of thin films are inexpensive and eco-friendly.