Abstract

This study investigated the electrochemical degradation of Cartap (in Padan 95 SP) at BDD electrode. BDD shows high electrochemical activity, high stability as indicated in their CVs and LSV although not really high oxygen evolution potential, which depends under experimental conditions. This study confirms that the degradation of Cartap was undergone via both direct and indirect oxidations. The influence of current density on Cartap degradation was investigated in detail, indicating the dependence of Cartap removal versus current density as represented in a quadratic function. Other important parameters were figured out: half-life t 1/2 = (315 min – 108 min) depending on the applied current density ( j from 5 mA·cm -2 to 20 mA·cm -2 ). Besides, we explored a calculation method for assessing the contribution of radical species as well as their production mechanism.

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