Abstract

Sustainability and environmental concerns have persuaded researchers to explore renewable materials, such as nature-derived polysaccharides, and add value by changing chemical structures with the aim to possess specific properties, like biological properties. Meanwhile, finding methods and strategies that can lower hazardous chemicals, simplify production steps, reduce time consumption, and acquire high-purified products is an important task that requires attention. To break through these issues, electrical discharging in aqueous solutions at atmospheric pressure and room temperature, referred to as the “solution plasma process”, has been introduced as a novel process for modification of nature-derived polysaccharides like chitin and chitosan. This review reveals insight into the electrical discharge in aqueous solutions and scientific progress on their application in a modification of chitin and chitosan, including degradation and deacetylation. The influencing parameters in the plasma process are intensively explained in order to provide a guideline for the modification of not only chitin and chitosan but also other nature-derived polysaccharides, aiming to address economic aspects and environmental concerns.

Highlights

  • In physics and chemistry, plasma is fundamentally defined as one of the four states of matter

  • Non-thermal equilibrium plasma can be induced by giving sufficient energy under a vacuum system; it can be generated under an atmospheric pressure environment by applying transient electrical or electrostatic discharges

  • Deacetylation is considered as a first step to functionalize chitin, which normally cannot dissolve in water and organic solvents, into other various derivates

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Summary

Introduction

Plasma is fundamentally defined as one of the four states of matter. Plasma can be artificially formed in the earth by giving sufficient thermal or electric energy supply, which ionizes the neutral gases to a quasi-neutral ionized gas [2]. Thermal equilibrium plasma can be generated by a strong electrical power and, usually, under gas pressure of more than 5 kPa. Its gas and electron temperatures are nearly equal. In non-thermal equilibrium plasma, the gas temperature is lower than the electron temperature [4]. Non-thermal equilibrium plasma can be induced by giving sufficient energy under a vacuum system; it can be generated under an atmospheric pressure environment by applying transient electrical or electrostatic discharges. Over the past several years, the the liquid-phase plasmas the plasmas have been along with gas-phase plasmas.

Solution
The powerthe supplies
Electrical Breakdown
Schematic
Formation of Reactive
Influencing Parameters in SPP under Aqueous Solutions
Chitin and Chitosan
Chitin
Chemical
10. Biological
Reduction of Molecular Weight and Destruction of Crystallinity Via SPP
Deacetylation of Chitin Via SPP
Findings
Conclusions and Future Aspects
Full Text
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