Insight into the law and mechanism of selective oxidation of Q&P steel under different annealing parameters

Abstract

In order to investigate the law and mechanism of selective oxidation of Quenching and Partitioning (Q&P) steel under different annealing parameters, the sensitivity of alloy elements added in Q&P steel to the annealing parameters was explored. Galvanizing experiments of QP steel were carried out at different annealing temperatures(770 °C and 730 °C) and different holding times(180 s and 300 s). The concentration change of selective oxidation element and the alloying element distribution in the coating were analyzed by Glow Discharge Optical Emission Spectrometer (GDOES), the morphology of surface oxides and inhibition layer were observed by Scanning Electron Microscope (SEM). The results showed that higher annealing temperature(770 °C) and longer annealing time(300 s) could both increase the concentration of Mn and Si on the surface of Q&P steel, improve the oxidation degree of steel surface, thin the inhibition layer, and lead to more leakage plating and deterioration of surface coating quality. The Mn depth profiles showing a parabolic trend and reaching its maximum value at about 20 nm below the surface, while the concentration of Si gradually decreases from the surface to the interior. The selective oxidation of Si and Mn are more sensitive to the annealing temperature than the annealing time.