Insight into the effects of Cu2+ ions and CuO species in Cu-SSZ-13 catalysts for selective catalytic reduction of NO by NH3

Abstract

Different Cu precursors were adopted to adjust the isolated Cu2+ ions and CuO species in the Cu-SSZ-13 catalysts. The Cu2+ ions were mainly located at eight-member rings in the catalysts with the Cu precursors of Cu(NO3)2 (Fresh-I) and CuSO4 (Fresh-II), while that located at six-member rings in the catalysts with the Cu precursors of CuCl2 (Fresh-III) and Cu(CH3COO)2 (Fresh-IV). All catalysts showed>90% of NO conversion and 100% of N2 selectivity at 200–680 °C. Fresh-I and Fresh-II catalysts showed an unexpected increase of the high-temperature activity after hydrothermal treatment. The characterizations revealed that the hydrothermal treatment promoted the production of CuO species, which accelerated the adsorption of NOx species to enhance the high-temperature SCR activity. Moreover, the SCR reaction pathway changed from Langmuir-Hinshelwood to Eley-Rideal mechanisms for the Fresh-II catalyst after the hydrothermal treatment, which was verified by in situ DRIFTS.