Insight into the effective electrocatalytic sulfide removal from aqueous solutions using surface oxidized stainless-steel anode and its desulfurization mechanism

Abstract

The electrochemical oxidation of hydrogen sulfide (H2S) has shown its potential for the real application of H2S emission control in wastewater treatment. In this study, a surface corrosion treatment of stainless steel (SS) was optimized by regulate Ni content in the oxide film on the SS AISI 304 surface for sulfide removal. The X-ray photoelectron spectroscopy and linear sweeping voltammetry results indicated a higher Ni content in the oxide film of surface-oxidized stainless steel (SOSS) attributed to a higher sulfide removal potential. Sulfide removal experiment results showed that SS-150 (with 150 s anodic pretreatment) anodes achieved the highest Ni content of 69% with the best sulfide removal efficiency, i.e., 97% within 48 h, which increased by 20% compared to the untreated SS. This study also demonstrated a strategy for in situ removal of deposited sulfur on the anodes by cathodic treatment at −0.38 V vs. RHE to alleviate the common issue of sulfur passivation. Density functional theory (DFT) calculation revealed that NiOOH was the major active species in SS-150 oxide film for a faster sulfide removal rate. The study developed a SS surface modification process for Ni content regulation that contributed to better sulfide removal efficiency.