Insight into the degradation of carbamazepine by electrochemical-pressure UV-activated peroxodisulphate process: kinetics, radicals, and degradation pathway

Abstract

ABSTRACT In this work, to improve the performance of peroxodisulphate-advanced oxidation, an electrochemical oxidation-assisted UV light-activated peroxodisulphate system (E/UV/PDS) was used to degrade carbamazepine. The degradation of carbamazepine by PDS, E/PDS, UV/PDS and E/UV/PDS systems was compared, and their synergistic effects were analysed. The influence of single factors, such as PDS addition, initial pH, DS voltage, target initial concentration, etc., on the degradation of the E/UV/PDS system was discussed, and the optimal degradation process parameters were given. The active substances were determined by free radical inhibition experiments, such as 1O2, SO 4 − ⋅ and ⋅ OH . It was proved that 1O2 contributes much more to the degradation of carbamazepine than SO 4 − ⋅ and ⋅ OH . The degradation pathway of carbamazepine was proposed. Finally, the degradation mechanism of carbamazepine in the E/UV/PDS system was speculated. The results indicate that the electrochemical combined with the E/UV/PDS system is of great potential application value in the removal of antibiotic drug pollution and environmental purification.