Abstract
Chemoselective by design is the total synthesis of marine pyrrole–imidazole alkaloids of the axinellamine/palau'amine/massadine class described by P. S. Baran and co-workers in their Communication on page 3581 ff. Their approach features unconventional transformations on completely unprotected polyamino and hydroxylated substrates and a new method for chemoselective oxidations in such settings.
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