Abstract

A thiol–aldehyde polycondensation was developed for the polymerization of phenolic compounds. In their Research Article (e202305677), Shichao Xu, Liang Yuan et al. found several catalysts for making linear and network-structured phenolic polymers from plant-derived monomers. Since the repeating units are connected via dynamic dithioacetal groups, the cross-linked networks can be reprocessed and oxidatively degraded by DMSO to recover the monomers for reuse.

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