Abstract

The excimer (a contraction of the excited-state dimer) is the most classical photoproduct which has been generally regarded as a trap site. In their Research Article (202114474), Hyungjun Kim, Frank Würthner, Dongho Kim and co-workers have captured the vibrational snapshots triggering the excimer formation and relaxation processes of the perylene bisimide folda-dimer using the ultrafast time-domain Raman spectroscopy. Understanding the mechanism of the excimer provides important criteria for designing the π-conjugated organic molecules.

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