Abstract
Atomically precise thiolate‐protected gold nanoclusters are ideal model systems for investigating the influencing factors of catalysis. In this work, three structurally related nanoclusters with reported star Au25 kernels have been synthesized to unify kernels‐isomerization, modification of peripheral ligands, electronic effects, and their correlation to catalytic performances into one system to design an efficient catalyst for oxidation of organosilanes. More details are given in the article by Zhang et al. on page 2575—2581.image
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