Abstract
A dinuclear nickel complex with a new double-decker structure, and its catalytic properties are described by D. Takeuchi, K. Osakada, et al. in their Communication on page 12536 ff. The complex promotes the copolymerization of ethylene with bifunctional monomers such as terminal dienes and unsaturated carboxylic esters. The close positioning of the nickel centers supported by the rigid macrocyclic ligand enhances the coordination of the bifunctional monomers and stabilize the growing polymer end.
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