Abstract

A fused Weitz/Wurster-type redox system has been prepared by fusing a central expanded radiaannulene core with two tetrathiafulvalene units. The system formally gains Hückel aromaticity by either oxidation (6π-dithiolium units) or reduction (14π-octadehydroannulene unit) and can exist in several redox states with characteristic UV/Vis/IR absorptions. More about this system can be found in the Communication by M. Brøndsted Nielsen and co-workers on page 6099 ff.

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