Abstract

Identification of catalytically active sites in heterogeneous catalysis is of great importance to both development of improved catalysts and investigation of intrinsic reaction mechanisms. In their Communication on page 9619 ff., X. Tang et al. discuss the accurate identification of the active site of selective catalytic reduction of nitrogen oxides by ammonia over a rod-shaped hollandite manganese oxide (HMO), which is located on the {100} side facet of the HMO rod and consists of surface lattice oxygen assembly with a semi-tunnel structural motif.

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