Abstract
AbstractInsertion reactions between a liquid germylene 1, and either a carbodiimide or dialkyl telluride lead to the formation of the group‐14‐metal(II) guanidinate complex 2 or the stable group‐14‐metal terminal alkyl tellurolate compound 3, respectively. The complexes 2 and 3 were structurally elucidated by multinuclear NMR and single‐crystal X‐ray crystallography. The use of 3 as a single‐source precursor (SSP) for the MOCVD of GeTe films was demonstrated. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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