Abstract
When mixtures of NaY or LaNaY zeolites with V2O5 or MoO3 are calcined in air at atmospheric pressure within given temperature and composition ranges, the oxides can migrate into the pores of the zeolite lattice. The extent of insertion is higher for LaNaY than for NaY; this is attributable to the space in the supercages left vacant by the migration of the La3+ ions into the sodalite cages or hexagonal prisms. Beyond certain temperature and oxide concentrations the NaY or LaNaY lattice is destroyed and new crystalline phases are formed. These solid-state interactions and reactions have been followed by X-ray diffraction (XRD) and by 27Al and 29Si magic-angle spinning (MAS) NMR.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society, Faraday Transactions
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
