Insertion of Dioxygen into a Platinum(II)−Methyl Bond To Form a Platinum(II) Methylperoxo Complex

Kyle A Grice,Karen I Goldberg

doi:10.1021/om8011272

Insertion of Dioxygen into a Platinum(II)−Methyl Bond To Form a Platinum(II) Methylperoxo Complex

Kyle A Grice, Karen I Goldberg

https://doi.org/10.1021/om8011272

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Journal: Organometallics	Publication Date: Jan 20, 2009
Citations: 76

Affiliation: University of Washington

#Insertion Of Dioxygen #Methyl Bond

Abstract
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Abstract

The platinum(II) complex (PN)PtMe2 (1; PN = 2-((di-tert-butylphosphino)methyl)pyridine) reacts with molecular oxygen in benzene or methylene chloride solutions to form (PN)PtMe(OOMe) (2), a platinu...

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