Abstract

A four-stage synthesis has been performed of the optically active (S)-(−)-diprionyl acetate in the form of an equimolar mixture of erythro-(2S,3S,7SR)- and threo-(2R,3S,7SR)-2-acetoxy-3,7-dimethylpentadecanes from a readily available chiral compound — (S)-(+)-3,7-dimethylocta-1,6-diene — with an overall yield of 13%.

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