Abstract

Abstract By reduction of sulfur nitride, S4N4, with hydrazine, N2H4, we have prepared all the seven eight-membered ring sulfurimines in the crystallized form. However, besides sulfurimine crystals, one notes the presence of elongated hexagonal crystals, which are very different in size and morphology. A study of these isolated crystals by: Chemical analysis. Infrared spectrography and U.V. spectrography. Radiocrystallography, shows that they are molecular charge-transfer complexes (C.T.C.), Hydrogen bond type: A few examples are given in Figure 11, in which are reported the chemical, crystallographical and spectroscopic results for solid octahedral sulfur derivatives.

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