Inorganic chemical composition and source signature of PM2.5 in Beijing during ACE-Asia period

Abstract

Aerosol samples for PM2.5 were collected in Beijing for 38 consecutive days from March to April 2001 using an IMPROVE Sampler. Concentrations of w0 elements in PM2.5 were determined using a PIXE method. Results show that he average mineral dust concentration of PM2.5 was 14.6 μg/m3 during the observation period. On the sanddust event days of March 21 and April 10, dust PM2.5 mass concentrations were 62.4 and 54.1 μg/m3, respectively. These demonstrate that fine particle pollution by dust event in Beijing was very severe. The enrichment factors of S and Cu reached minimums on the dusty days and were high on the non-dusty days. It is considered that enrichment factors of elements in PM2.5, which are associated with human activities, can probably provide an effective method to distinguish local sources from external sources of dust. Factor analysis on the chemical composition in PM2.5 shows that sources of crustal matters, anthropogenic emission, and oil combustion contributed to PM2.5 levels in air in the springtime of 2001 in Beijing.