Innovative strategies for enhancing gas separation: Ionic liquid-coated PES membranes for improved CO2/N2 selectivity and permeance

Abstract

As a cost-effective advancement in membrane technology, this study investigates the impact of PEG additive and CBT on the structural, stability, and gas permeance properties of PES-coated membranes, utilizing 1-dodecyl-3-methylimidazolium chloride ionic liquid ([DDMI][Cl] IL) as a carrier liquid. BET and FT-IR analyses highlight the significant enhancement in performance through the immobilization of pores with [DDMIM][Cl] IL. The investigation focuses on PES-M5-coated membranes, revealing excellent stability in finger-like pore structures prepared through direct immersion and nitrogen pressure immobilization. PES-M5-coated membranes with [DDMIM][Cl] IL via direct immersion experience lower weight loss than those coated using nitrogen pressure, with critical pressures at 1.4 and 1.25 bar, respectively. The study identifies PES-coated membranes, particularly PES-M25 (20.88 GPU) with macro-void pores and PES-M5 (29 GPU) with finger-like pores, exhibiting the highest CO2 permeance and CO2/N2 selectivity. As a cost-effective advancement in membrane technology, ionic liquids are employed in support membranes to enhance gas separation. Employing pure PES membranes with varying pore structures, created through the NIPS method, the study immobilizes [DDMI][Cl] IL in membrane pores through nitrogen pressure and direct immersion. Results underscore the successful application of porous support materials coated with ionic liquids for continuous CO2 and sulfur compound separation, showcasing competitive permeability and selectivity compared to traditional polymer membranes.