Inhomogeneous Large Deformation Study on Magneto-Thermal Sensitive Hydrogels

Abstract

Due to the incorporation of magnetic nanoparticles (MNPs), magnetically tuneable hydrogels have attracted considerable attention recently due to their ability to undergo remotely controlled large deformation. This work investigates the mechanics of the large deformation from the thermodynamics perspective for magneto-thermal sensitive hydrogels. The chemical thermodynamics of a temperature sensitive gel is first recapped before moving on to the thermodynamics of magnetism. Furthermore, an explicit energy form for the magneto-thermal sensitive hydrogel is adopted. The proposed field theory is implemented in a finite element method through the UHYPER subroutine. The finite element simulation results have been validated with analytical solutions at various temperatures and magnetic field strengths for MNPs entrapped PNIPAM hydrogel. We also utilize the numerical models to explain the interesting phenomena, including micro valves, bifurcation, and the opening of gel capsule for drug release delivery. The numerical deformation pattern for bifurcation is consistent with the experimental pattern, thus illustrating our theory and numerical method can provide future perspectives for device design of magneto-thermal sensitive hydrogel.