Abstract

The present study aims to explore the effect of 2-nitroacridone, an antimicrobial compound, on low carbon steel (LCS) corrosion in acid solution (1M HCl). The compound was tested at various concentrations (0.001−10mM) and five temperatures (25, 35, 45, 55, and 65°C) to determine the optimal concentration and temperature range for the best corrosion inhibiting effect. In evaluating the inhibition efficiency, weight loss measurement, potentiodynamic polarization measurement, electrochemical impedance spectroscopy, SEM/EDAX/AFM and DFT measurements were used. The inhibition efficiency increases with the increase in concentration and decreases with temperature. The maximum inhibition efficiency was found (94.96%) at 25°C in the presence of 5mM concentration of the studied compound. The various adsorption isotherms were also explored to find the best fit, which was found to obey the Langmuir adsorption isotherm. The thermodynamic parameters (Ea, Kads, ΔG°ads) have also been calculated and discussed. The potentiodynamic polarization study revealed that 2-nitroacridone behaved as a mix-type of inhibitor that predominantly inhibited the anodic reaction. Moreover, a correlation between the inhibition efficiency of the studied compound and certain molecular parameters were determined by quantum chemical computations.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.