Inhibition of turbulent methane/air premixed bunsen flames by dimethyl methylphosphonate

Abstract

There is little knowledge about the inhibition efficiency of dimethyl methylphosphonate (DMMP) against turbulent flames, in which vortices of different sizes corrugate and stretch the flame front. This study is to investigate the performance and the mechanism of DMMP in inhibiting turbulent methane/air premixed Bunsen flames. Several important parameters are chosen to characterize the combustion of the flames, including flame brush height, flame brush thickness and turbulent burning velocity. It is found that the flame brush expands both horizontally and vertically with the increase of turbulent intensity. For all the flames, the centerline mean flame brush thickness increases linearly with flame height. Turbulent burning velocity decreases monotonically with the increasing of DMMP addition. However, the normalized turbulent burning velocity increases with the normalized turbulent intensity. Compared with the performance in laminar premixed flames, the inhibition efficiency depends on the turbulent intensity. For low-intensity turbulent flames, the inhibition efficiency is higher than that in laminar premixed flames, but the relative inhibition efficiency decreases with DMMP addition. This can be attributed to the relative size of the vortices and the flame front thickness: when the Kolmogorov length scale is less than the preheat zone thickness but greater than the reaction zone thickness, vortices reduce the burning velocity; when the Kolmogorov length scale is less than the reaction zone thickness, vortices facilitate the combustion. The trend is opposite in high-intensity turbulent flames, which is mainly attributed to the generating of the flame pockets in the flame tips.