Inhibition of grain growth in liquid-phase sintered SiC ceramics by AlN additive and spark plasma sintering

Abstract

SiC ceramics were prepared from nanosized β-SiC powder with different compositions of AlN and Y 2O 3 sintering additives by spark plasma sintering (SPS) at 1900 °C for 600 s in N 2. The relative density of the sintered SiC specimens increased with increasing amount of AlN, reaching a relative density higher than 99%, while at the same time grain size decreased significantly. The smallest average grain size of 150 nm was observed for SiC sample sintered with 10 vol% of additives consisting of 90 mol% AlN and 10 mol% Y 2O 3. Fully dense nanostructured SiC ceramics with inhibited grain growth were obtained by the AlN additive and SPS technique. The flexural strength of the SiC body containing 70 mol% AlN and 30 mol% Y 2O 3 additives reached the maximum value of 1000 MPa. The SiC bodies prepared with AlN and Y 2O 3 additives had the fracture toughness of around 2.5 MPam 1/2.