Inhibition Effect of Coal Spontaneous Combustion by Composite Inhibitory Foam Based on CaCl2-Melatonin Inhibitor.

Abstract

Inhibitory foam technology plays an important role in inhibiting coal spontaneous combustion. To enhance the stability and inhibitory performance of inhibitory foam for coal spontaneous combustion, a novel physicochemical composite inhibitor was developed in this work. CaCl2 was chosen as an inorganic salt physical inhibitor to compound with the chemical inhibitor melatonin (MLT) due to its corresponding good foam stability. When the mass ratio of CaCl2 to MLT was 4:1, the lowest CO release concentration of 7337.06 ppm at 200 °C was observed in the composite inhibitor-treated coal. Furthermore, the addition of 20 wt % of the composite inhibitor resulted in a foam half-life of 3067 min, which was 5.89 times longer than that of the water-based foam. In comparison with the water-based foam, the inhibitory foam based on 20 wt % CaCl2-MLT composite inhibitor exhibited more excellent foam stability, wetting ability, and inhibition performance. The release of CO at 200 °C was 7854.6 ppm, showing a reduction of 63.2% compared to the raw coal. Moreover, the composite inhibitory foam could significantly delay the onset of the characteristic temperature and reduce the weight change during the decomposition stage by 12.8%.