Abstract
The IR study of a series of heterometallic vinylidene-bridged complexes CP(CO) 2MnM( μ-C = CHPh)LL′, where M = Pt or Pd, L and L′ = CO, tert-phosphites, PPh 3, Ph 2P(CH 2) nPPh 2, n = 1–3, demonstrated the existence of a gradual transformation of one of the terminal CO groups at the Mn atom into bridging one spanning the Mn-M bond, which goes through the intermediate semi-bridging form and is induced by the electron-donating capacities of ligands L and L′ at the M atom.
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