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Abstract
The non-dissociative adsorption of triethylamine on rutile involves the formation of hydrogen bonds between surface hydroxyl groups and triethylamine molecules and coordinative interactions between triethylamine and Lewis-acidic surface sites. There is no evidence for the Bronsted acidity of hydroxyl groups.Dissociative chemisorption of triethylamine involves surface hydroxyl groups and generates adsorbed diethylamine, ethoxide ions and acetate ions as products. One type of hydroxyl group is completely unreactive towards triethylamine.
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Schedule a callMore From: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
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