Abstract
The IR spectra of polycrystalline Mg(OH) 2 and Mg(OD) 2 are reported in the 4000–40 cm −1 region. Band assignments were discussed on the basis of isotopic band shifts of the fundamental vibrations by combining the results of factor group analysis for D 3d 3 crystal structure with the Teller–Redlich product rule for crystal vibrations. The band assignments proposed are different from the previous IR spectroscopic studies.
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