Abstract
We study theoretically and experimentally the infrared absorption spectrum of C 2F radical. The calculated spectrum of C 2F shows characteristic bands at ca. 1600 cm −1 and rich absorption patterns above 4500 cm −1 with very high intensities (up to ∼10 4 km mol −1). In experiment, C 2F radicals were obtained by ultraviolet photolysis of HCCF in Ar and Kr matrices at 9 K. The experimental evidence and good agreement with the theoretical results allow us to report for the first time the experimental spectrum of C 2F radical. In agreement with theory, the C 2F absorption bands are very strong in the experimental spectra compared to the bands of C 2H and HCCF.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
