Abstract
Infrared spectra of CHF 2Cl dimer and the CHF 2Cl⋯H 2O complex have been observed in Xe matrix. A comparison of the spectra with the results of DFT calculations led us to the following conclusion: the structure of CHF 2Cl dimer is a head-to-tail type with intermolecular Cl⋯H interaction, whereas CHF 2Cl⋯H 2O has a C–H⋯O intermolecular hydrogen bond, in contrast with the analogous CH 3F⋯H 2O complex [Y. Futami, S. Kudoh, M. Takayanagi, M. Nakata, Chem. Phys. Lett. 357 (2002) 209].
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